The International Space Station was in position to view the umbral (ground) shadow cast by the moon as it moved between Earth and the sun during a solar eclipse on March 29, 2006. This astronaut image captures the umbral shadow across southern Turkey, northern Cyprus and the Mediterranean Sea.
Source: http://www.nasa.gov
NASA TV, which is online, has a live feed, if you happen to be up at 6 a.m.
The video will most likely be archived, and will be linked and/or posted here as well.